Elemental Geochemistry of the Upper Cretaceous Rakb Formation in Well C3-65, Sarir Field, Sirte Basin, NE Libya
DOI:
https://doi.org/10.71147/mmpnge43Keywords:
Elemental Geochemistry, Rakb Formation, Sarir Field, Sirte Basin, LibyaAbstract
Assessing the elemental geochemistry of the Rakb Formation in well C3-65, Sarir Field, Sirte Basin, was the goal of this work. The results demonstrated that the Rakb Formation is classified as silica-rich argillaceous shale as indicated by the content of quartz and clay minerals. Numerous sources contribute to the Rakb Formation, including igneous (mafic, intermediate, and felsic rocks) and sedimentary (quartzose rocks), as showed by the plots of Al2O3 versus TiO2, SiO2 versus FeO, CaO versus Na2O, F1 versus F2, and SiO2/10-CaO-MgO-Na2O+K2O. Several parameters, including Fe/Al, Mn*, and SO3, suggested that the Rakb Formation's proven depositional setting is the shallow anoxic marine environment. The plots of MgO versus Fe2O3, Al2O3 versus P2O5, Ca versus Fe, and CaO versus MgO supported this assumption. There was clear terrestrial input during deposition as indicated by the Ti/Al and Al/(Al+Fe) ratios. The Rakb Formation is considered part of the coastal facies as presented by the plot of Al2O3/(Al2O3+Fe2O3) versus Fe2O3/TiO2. The Rakb Formation is not significantly affected by severe diagenesis as confirmed by the plots of CaO/Al2O3 versus P2O5/Al2O3. According to the paleoweathering indices (RR, CIA, CIW, PIA, and CIW´), the source area experienced moderate to high levels of paleoweathering intensity. Conditions during deposition were mostly semi-arid to semi-humid, as verified by the CIA, K2O/Al2O3, and T values. The studied sediments are obviously immature, based on the ICV values. Paleoproductivity fluctuated from low to high as displayed by the P/Al and P/Ti ratios. Th plots of Al2O3/(100-SiO2) versus Fe2O3/(100-SiO2), SiO2 versus K2O/Na2O, and SiO2/20-K2O+Na2O-TiO2+Fe2O3+MgO confirmed that he paleotectonic environment of the Rakb Formation is the continental margin.
References
Aboglila, S., Grice, K., Trinajstic, K., Dawson, D. and Williford, K.H. (2010). Use of biomarker distributions and compound specific isotopes of carbon and hydrogen to delineate hydrocarbon characteristics in the east Sirte Basin (Libya). Organic Geochemistry, 41(12), 1249-1258.
Aboglila, S., Grice, K., Trinajstic, K., Snape, C. and Williford, K.H. (2011). The significance of 24-norcholestanes, 4-methylsteranes and dinosteranes in oils and source-rocks from east Sirte Basin (Libya). Applied Geochemistry, 26, 1694-1705.
Aboglila, S. and Elkhalgi, M. (2013). Organic geochemical evaluation of Cretaceous potential source rocks, east Sirte Basin, Libya. International Journal of Geosciences, 4, 700-710.
Barr, F.T. and Weegar, A.A. (1972). Stratigraphic nomenclature of the Sirte Basin, Libya. Petroleum Exploration Society of Libya, Tripoli, 179p.
Bellanca, A., Claps, M., Erba, E., Masetti, D., Neri, R., Premoli-Silva, I. and Venezia, F. (1996). Orbitally induced limestone/marlstone rhythms in the Albian-Cenomanian Cismon section (Venetian región, northern Italy): sedimentology, calcareous and siliceous plankton distribution, elemental and isotope geochemistry. Palaeogeography, Palaeoclimatology, Palaeoecology, 126, 227-260.
Canfield, D.E. (1994). Factors influencing organic carbon preservation in marine sediments. Chemical Geology, 114, 315-329.
Cao, Y., Songa, H., Algeo, T.J., Chu, D., Du, Y, Tian, L., Wang, Y. and Tong, J. (2019). Intensified chemical weathering during the Permian-Triassic transition recorded in terrestrial and marine successions. Palaeogeography, Palaeoclimatology, Palaeoecology, 519, 166-177.
Cox, R., Low, D.R. and Cullers, R.L. (1995). The influence of sediment recycling and basement composition on evolution of mudrock chemistry in the southwestern United States. Geochimica et Cosmochimica Acta, 59, 2919-2940.
Crook K.A.W. (1974). Lithogenesis and geotectonics: The significance of compositional variation in flysch arenites (greywackes). Society for Sedimentary Geology Special Publication (SEPM), 19, 304-310.
Cullers, R.L. (2000). The geochemistry of shales, siltstones, and sandstones of Pennsylvanian-Permian age, Colorado, USA: Implication for provenance and metamorphic studies. Lithos, 51, 181-203.
Cullers, R.L. and Podkovyrov, V.N. (2000). Geochemistry of the Mesoproterozoic Lakhanda shales in southeastern Yakutia, Russia: Implications for mineralogical and provenance control, and recycling. Precambrian Research, 104, 77-93.
Dhannoun, H.Y. and Al-Dlemi, A.M.S. (2013). The relation between Li, V, P2O5, and Al2O3 contents in marls and mudstones as indicators of environment of deposition. Arabian Journal of Geosciences, 6, 817-823.
EIA (U.S. Energy Information Administration, 2015). Technically recoverable shale oil and shale gas resources: Libya. Technical Report, 26p.
El-Mehdawi, A.D. (1998). Odontochitina tabulata sp. nov. A Late Santonian-Early Campanian dinoflagellate cyst from SE Sirte Basin, Libya. Journal of Micropalaeontology, 17, 173-178.
Fedo, C.M.; Nesbitt, H.W. and Young, G.M. (1995). Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols, with implications for paleoweathering conditions and provenance. Geology, 23, 921-924.
Gamero-Diaz, H., Miller, C. and Lewis, R. (2012). sCore: A classification scheme for organic mudstones based on bulk mineralogy. American Association of Petroleum Geologists (AAPG), Search and Discovery Article #40951.
Hallett, D. (2002). Petroleum geology of Libya. Amsterdam, Elsevier Inc., 503p.
Hallett, D. and Clark-Lowes, D. (2016). Petroleum geology of Libya. 2nd edition, Amsterdam, Elsevier Inc., 404p.
Harnois, L. (1988). The CIW index: A new chemical index of weathering. Sedimentary Geology, 55, 319-322.
Hasterok, D., Gard, M., and Webb, J. (2018). On the radiogenic heat production of metamorphic, igneous, and sedimentary rocks. Geoscience Frontiers, 9(6), 1777-1794.
Hayashi, K., Fujisawa, H., Holland, H. and Ohmoto, H. (1997). Geochemistry of ∼1.9 Ga sedimentary rocks from northeastern Labrador, Canada. Geochimica et Cosmochimica Acta, 61(19), 4115-4137.
He, C., Ji, L., Su, A., Wu, Y., Zhang, M., Zhou, S., Li, J., Hao, L. and Ma, Y. (2019). Source-rock evaluation and depositional environment of black shales in the Triassic Yanchang Formation, southern Ordos Basin, north-central China. Journal of Petroleum Science and Engineering, 173, 899-911.
He, J., Zhou, Y. and Li, H. (2011). Study on geochemical characteristics and depositional environment of Pengcuolin chert, Southern Tibet. Journal of Geography and Geology, 3(1), 178- 188.
Herron, M.M. (1988). Geochemical classification of terrigenous sandstone and shale from core and log data. Journal of Sedimentary Petrology, 5(8), 820-829.
Ibe, C.U. and Okon, E.E. (2021). Provenance and tectonic settings of the Eze‑Aku Sandstone (Turonian) in Awajir and adjoining areas, Southern Benue Trough, Nigeria: evidence from petrography and geochemistry. Journal of Sedimentary Environments, 6, 237-254.
Khan, D., Zijun, L., Qiu, L., Kuiyuan, L., Yongqiang, Y., Cong, N., Bin, L., Li, X. and Habulashenmu, Y. (2023). Mineralogical and geochemical characterization of lacustrine calcareous shale in Dongying Depression, Bohai Bay Basin: Implications for paleosalinity, paleoclimate, and paleoredox conditions. Geochemistry, 83(3), 125978.
Kronberg, B.I. and Nesbitt, H.W. (1981). Quantification of weathering, soil geochemistry and soil fertility. Journal of Soil Science, 32(3), 453-459.
Kroonenberg S.B. (1994). Effects of provenance, sorting and weathering on the geochemistry of fluvial sands from different tectonic and climatic environments. 29th International Geology Congress, Proceeding Book, Part A, 69-81.
Liu, Z.H., Zhuang, X.G., Teng, G.E., Xie, X.M., Yin, L.M., Bian, L.Z., Feng, Q. and Algeo, T. (2015). The Lower Cambrian Niutitang Formation at Yangtiao (Guizhou, SW China): Organic matter enrichment, source rock potential, and hydrothermal influences. Journal of Petroleum Geology, 38, 411-432.
Lyons, T.W. and Severmann, S. (2006). A critical look at iron paleoredox proxies: New insights from modern euxinic marine basins. Geochimica et Cosmochimica Acta, 70(23), 5698-5722.
Machhour, L., Philip, J. and Oudin, J.L. (1994). Formation of laminate deposits in anaerobic-dysaerobic marine environments. Marine Geology, 117, 287-302.
McLennan, S.M., Hemming, S., McDaniel, D.K. and Hanson, G.N. (1993). Geochemical approaches to sedimentation, provenance, and tectonics. In Johnson, M.J. and Basu, A. (eds), Processes Controlling the Composition of Clastic Sediments. Geological Society of America, Special Paper, 284, 21-40.
Murphy, A.E., Sageman, B.B., Hollander, D.J., Lyons, T.W. and Brett, C.E. (2000). Black shale deposition and faunal overturn in the devonian appalachian basin: clastic starvation, seasonal water-column mixing, and efficient biolimiting nutrient recycling. Paleoceanography, 15(3), 280-291.
Naseem, S., Naseem, S. and Sheikh, S.A. (2005). Geochemical evaluation of depositional environment of Parh Limestone, Southern Pab Range, Balochistan, Pakistan. SPE/PAPG Annual Technical Conference, Islamabad, pp. 1-9.
Nesbitt, H.W. and Young, G.M. (1982). Early Proterozoic climates and plate motions inferred from major element chemistry of lutites. Nature, 299, 715-717.
Pettijohn, F.J. (1975). Sedimentary rocks. 2nd edition, Harper and Row Publishers, 628 p.
Ratcliffe, K.T., Morton, A.C., Ritcey, D.H. and Evenchick, C.A. (2007). Whole-rock geochemistry and heavy mineral analysis as petroleum exploration tools in the Bowser and Sustut basins, British Columbia, Canada. Bulletin of Canadian Petroleum Geology, 55(4), 320-336.
Roser, B.P., and Korsch, R.J. (1986). Determination of tectonic setting of sandstone-mudstone suites using SiO2 content and K2O/Na2O ratio. Journal of Geology, 94, 635-650.
Roser, B.P., and Korsch, R.J. (1988). Provenance signatures of sandstone- mudstone suites determined using discriminant function analysis of major-element data. Chemical Geology, 67, 119-139.
Roy, D.K. and Roser, B.P. (2013). Climatic control on the composition of Carboniferous–Permian Gondwana sediments, Khalaspir Basin, Bangladesh. Gondwana Research, 23(3), 1163-1171.
Ruxton, B.P. (1968). Measures of degree of chemical weathering of rocks. The Journal of Geology, 76(5), 515-527.
Saadawi, D.A., Ibrahim, A.M., AlSaad, H.A., Kamel, S.A. and Shalaby, A.M. (2023). Mineralogy and geochemistry of the Upper Cretaceous mudrocks, Wadi Feiran region, west-central Sinai, Egypt. Iraqi Geological Journal, 56(1F), 260-278.
Shaltami, O.R. (2024). Elemental geochemistry of the Awainat Wanin Formation in three selected areas, Murzuq Basin, SW Libya. Global Scientific Journals (GSJ), 12(2), 992-1016.
Shaltami, O.R., Algomati, A.E., and Geniber, O.A. (2024). Geochemistry of Al Mahruqah Formation: A case study of four areas in the northern Murzuq Basin, SW Libya. Libyan Journal of Engineering Science and Technology (LJEST), 4(1), 76-84.
Suttner, L.J. and Dutta, P.K. (1986). Alluvial sandstone composition and paleoclimate. Framework mineralogy. Journal of Sedimentary Petrology, 56, 326-345.
Taylor, S.R. and McLennan, S.M. (1985). The continental crust: Its composition and evolution. Blackwell Scientific Publishers, Oxford, 312p.
Wedepohl, K.H. (1978). Manganese: abundance in common sediments and sedimentary rocks. In Wedepohl, K.H. (eds), Handbook of Geochemistry. Berlin, Springer, II/3, 1-17.
Williams, J.J. (1972). Augila field, Libya: Depositional environment and diagenesis of sedimentary reservoir and description of igneous reservoir. In: Stratigraphic oil and gas fields; classification exploration methods and case histories (ed. R.E. King). American Association of Petroleum Geologists (AAPG), 16, 623-632.
Yang, M., Zuo, Y., Fu, X., Qiu, L., Li, W., Zhang, J., Zheng, Z. and Zhang, J. (2022). Paleoenvironment of the Lower Ordovician Meitan Formation in the Sichuan Basin and adjacent areas, China. Minerals, 12(1), 75.
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